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Journal de Physique I 3, 3 (1993) 855-862
Anomalous excitation profile and its relationship to multiple dopant sites in (Nd, Cr) YAlO3
P. Nelson, L. Lou, G. Boulon, C. Garapon, C. Pedrini
(1993)

Excitation spectra of (Nd3+, Cr3+)YAlO3 are presented which show anomalous profiles. We demonstrate that these anomalous lineshapes can be explained by a combination of three physical mechanisms: the existence of several inequivalent Nd sites, the existence of significant energy transfer from Cr3+ to Nd3+ and strong absorption of the excitation beam by Nd3+ ions. Reasons for residual asymmetry in excitation profiles are discussed with particular emphasis on a Fano effect.
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