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Au cours de ce travail, nous avons effectué une étude méthodologique pour la préparation de banques de triazoles, en utilisant la réaction de la chimie " clic ". Ces études ont démontré que la réaction entre un alcyne vrai activé et un azoture est possible dans les conditions sans solvant et sans catalyseur pour conduire un mélange d'isomères 1,4 et 1,5 avec un rendement moyen de 76%. Nous avons remarqué que l'addition des métaux (SiO2, MgCl2, Al2O3, FeCl3 et CuCl2) permettait d'améliorer les rendements des réactions, et on a observé que la silice est la meilleur catalyseur, alors que la catalyse au cuivre (I) donne une sélectivité complète pour l'isomère 1,4. Ce résultat est bien confirmé par l'étude de la régiosélectivité qui montre que les molécules contenant deux types d'alcynes (activé et non activé) peuvent êtres fonctionnalisés séquentiellement et sélectivement. Nous avons aussi préparé les bis-triazoles en deux étapes : la première sur l'alcyne activé sans catalyseur et la deuxième étape se fait sur l'alcyne non activé par catalyse au cuivre (I), ce qui permet de dire que les alcynes terminaux portant un groupement carbonyle en de la triple liaison sont beaucoup plus réactifs.Nous avons également pu étendre l'application de la catalyse supportée dans la réaction de Huisgen dans les domaines de la synthèse de dérivés de produits naturels et d'éthers couronne. En utilisant la synthèse classique et en flux continu, nous avons pu préparer des structures originales dérivées de l'acide quinique porteuse de cycles triazoliques. Ces composés seront testés pour leur activité biologique. Nous avons également entrepris la synthèse de dérivés nouveaux d'éthers couronnes azotes afin d'incorporer à ces structures des bras contenant un ou deux noyaux triazoles. L'obtention de ces substances permettra d'ouvrir l'étude de leur propriétés complexantes dans l'avenir
Les diverses perovskites de strontium-fer présentent de très fortes corrélations entre la structurecristalline et les phénomènes d'ordre de lacunes d'oxygènes, de charge, de spin et d'orbitales. Danscette thèse, nous avons réalisé une étude systématique des relations entre les ordres de charges etles ordres de spins selon les différents environnements cristallographiques rencontrés pour lescations Fe3+ et Fe4+ dans la phase Sr4Fe4O11, pour le cation Fe3+ dans les phases Sr3Fe2O6 et Sr2Fe2O10et pour le cation Fe2+ dans la phase SrFeO2. Les synthèses des phases polycristallines furent réaliséesvia des voies " solide " ou " sol-gel " en complément de la synthèse de cristaux préparés à l'aide d'unfour à image à fusion de zone verticale pour les phases Sr4Fe4O11 et Sr2Fe2O10. La qualité cristalline etchimique des oxydes fut contrôlée par diffraction de rayons X sur poudre et spectroscopieMössbauer alors que l'étude de la structure électronique de chaque phase a été réalisée à l'aide despectroscopie d'absorption de rayons X. Finalement, les structures magnétiques des phases Sr3Fe2O6et Sr4Fe4O11 sont aussi présentées.
Double-walled carbon nanotubes (DWNTs), produced by a catalytic chemical vapor deposition method, have been fluorinated using a volatile mixture of BrF3 and Br2. Optical absorption spectroscopic study on the product detected nonfluorinated nanotubes, which could correspond to the inner walls of DWNTs. The fluorinated DWNTs have been annealed in vacuum at fixed temperatures, and X-ray photoelectron spectroscopy showed almost no fluorine in the sample heated to 300 °C. Comparison between X-ray fluorescent C KR spectra of the pristine DWNT sample and the annealed fluorinated sample revealed change of the atomic structure of graphitic shells in the process of thermal defluorination.
We present a mathematical study of the order book as a multidimensional continuous- time Markov chain where the order flow is modeled by independent Poisson processes. Our aim is to bridge the gap between the microscopic description of price formation (agent- based modeling), and the Stochastic Differential Equations approach used classically to describe price evolution at macroscopic time scales. To do this, we rely on the theory of infinitesimal generators and Foster-Lyapunov stability criteria for Markov chains. We motivate our approach using an elementary example where the spread is kept constant ("perfect market making"). Then we compute the infinitesimal generator associated with the order book in a general setting, and link the price dynamics to the instantaneous state of the order book. In the last section, we prove that the order book is ergodic - in particular it has a stationary distribution - that it converges to its stationary state exponentially fast, and that the large-scale limit of the price process is a Brownian motion.
In this paper, we consider a discrete time economy where we assume that the short term interest rate follows a quadratic term structure of a regime switching asset process. The possible non-linear structure and the fact that the interest rate can have different economic or financial trends justify the interest of Regime Switching Quadratic Term Structure Model (RS-QTSM). Indeed, this regime switching process depends on the values of a Markov chain with a time dependent transition probability matrix which can well captures the different states (regimes) of the economy. We prove that under this modelling that the conditional zero coupon bond price admits also a quadratic term structure. Moreover, the stochastic coefficients which appear in this decomposition satisfy an explicit system of coupled stochastic backward recursions.
In this note, we cast a Hawkes process-based order book model into a markovian setting and; using techniques from the theory of Markov chains and stochastic stability, show that the order book is stable and leads to a diffusive price limit at large time scales.
We consider allocation problems that arise in the context of service allocation in Clouds. More specifically, we assume on the one part that each computing resource is associated to a capacity constraint, that can be chosen using Dynamic Voltage and Frequency Scaling (DVFS) method, and to a probability of failure. On the other hand, we assume that the service runs as a set of independent instances of identical Virtual Machines. Moreover, there exists a Service Level Agreement (SLA) between the Cloud provider and the client that can be expressed as follows: the client comes with a minimal number of service instances which must be alive at the end of the day, and the Cloud provider offers a list of pairs (price,compensation), this compensation being paid by the Cloud provider if it fails to keep alive the required number of services. On the Cloud provider side, each pair corresponds actually to a guaranteed success probability of fulfilling the constraint on the minimal number of instances. In this context, given a minimal number of instances and a probability of success, the question for the Cloud provider is to find the number of necessary resources, their clock frequency and an allocation of the instances (possibly using replication) onto machines. This solution should satisfy all types of constraints during a given time period while minimizing the energy consumption of used resources. We consider two energy consumption models based on DVFS techniques, where the clock frequency of physical resources can be changed. For each allocation problem and each energy model, we prove deterministic approximation ratios on the consumed energy for algorithms that provide guaranteed probability failures, as well as an efficient heuristic, whose energy ratio is not guaranteed.
We give an overview of recent work on the rule-based modeling of nano devices. In particular, our experience in the modeling of a nanoscale elevator suggested us to enhance rule-based modeling with complex functional rates that can be used to express rates that depend on the current state of the entire complexes in which the reacting molecules reside.
Rule-based languages (like, for example, Kappa, BioNetGen, and BioCham) have emerged as successful models for the representation, analysis, and simulation of bio-chemical systems. In particular Kappa, although based on reactions, differs from traditional chemistry as it allows for a graph-like representation of complexes. It follows the "don't care, don't write" approach: a rule contains the description of only those parts of the complexes that are actually involved in a reaction. Hence, given any possible combination of complexes that contain the reactants, such complexes can give rise to the reaction. In this paper we address the problem of extending the "don't care, don't write" approach to cases in which the actual structure of the complexes involved in the reaction could affect it (for instance, the mass of the complexes could influence the rate). The solutions that we propose is κ F , an extension of the Kappa-calculus in which rates are defined as functions of the actually involved complexes.
Fifty years ago, FitzHugh introduced a phase portrait that became famous for a twofold reason: it captured in a physiological way the qualitative behavior of Hodgkin-Huxley model and it revealed the power of simple dynamical models to unfold complex firing patterns. To date, in spite of the enormous progresses in qualitative and quantitative neural modeling, this phase portrait has remained a core picture of neuronal excitability. Yet, a major difference between the neurophysiology of 1961 and of 2011 is the recognition of the prominent role of calcium channels in firing mechanisms. We show that including this extra current in Hodgkin-Huxley dynamics leads to a revision of FitzHugh-Nagumo phase portrait that affects in a fundamental way the reduced modeling of neural excitability. The revisited model considerably enlarges the modeling power of the original one. In particular, it captures essential electrophysiological signatures that otherwise require non-physiological alteration or considerable complexification of the classical model. As a basic illustration, the new model is shown to highlight a core dynamical mechanism by which calcium channels control the two distinct firing modes of thalamocortical neurons.
Positive polynomial matrices and linear matrix inequalities (LMI) can be used to design linear parameter varying (LPV) controllers depending polynomially on the scheduling parameters, and robust to polynomial parametric uncertainty. The salient features of the approach are (a) the ability to design a controller of order and structure fixed a priori; (b) the use of a transfer function, or polynomial modeling framework that bypasses difficulties typically encountered with canonical state-space representations of LPV controllers; (c) the existence of a user-friendly Matlab interface to model this class of LMI problems. The main limitation of the approach is the choice of a nominal, or central characteristic polynomial around which the design is carried out.
In this paper we study the Poisson and heat equations on bounded and unbounded domains with smooth boundary with random Dirichlet boundary conditions. The main novelty of this work is a convenient framework for the analysis of such equations excited by the white in time and/or space noise on the boundary. Our approach allows us to show the existence and uniqueness of weak solutions in the space of distributions. Then we prove that the solutions can be identified as smooth functions inside the domain, and finally the rate of their blow up at the boundary is estimated. A large class of noises including Wiener and fractional Wiener space time white noise, homogeneous noise and Lévy noise is considered.
An experimental approach is presented in order to study the evolution of the spreading of a macro-drop of liquid metal. The objective of this work is to supply qualitative and quantitative information during the deposit of liquid metal in static pulsed Gas Metal Arc Welding (P-GMAW). The experimental results are analyzed in the light of dimensionless numbers in order to identify the involved physical mecanisms and appreciate the heat and mass e ects on the behavior of such a macro-drop.
Several compositions of metal cored filler wire were manufactured to define the best welding conditions for homogeneous welding, by Gas Metal Arc Welding (GMAW) process, of a modified AISI 444 ferritic stainless steel dedicated to automotive exhaust manifold applications. The patented grade is know under APERAM trade name K44X and has been developed to present improved high temperature fatigue properties. All filler wires investigated contained 19%Cr and 1.8%Mo, equivalent to the base metal K44X chemistry, but various titanium and niobium contents. Chemical analyses and microstructural observations of fusion zones revealed the need of a minimum Ti content of 0.15% to obtain a completely equiaxed grain structure. This structure conferred on the fusion zone a good ductility even in the as-welded state at room temperature. Unfortunately, titanium additions decreased the oxidation resistance at 950°C if no significant Nb complementary alloying was made. The combined high Ti and Nb additions made it possible to obtain for the welded structure, after optimized heat treatment, high temperature tensile strengths and ductility for the fusion zones and assemblies, rather close to those of the base metal. 950°C aging heat treatment was necessary to restore significantly the ductility of the as welded structure. Both fusion zone and base metal presented rather homogenized properties. Finally, with the optimized composition of the cored filler wire - 0.3 Ti minimum (i.e. 0.15% in the fusion zone) and high Nb complementary additions, the properties, including the thermal fatigue strength, of the K44X assemblies are excellent.
Seven compositions of metal cored filler wires for Gas Metal Arc Welding (GMAW), containing the same weight percent of chromium (Cr) and molybdenum (Mo) as 444 steel, but with different titanium (Ti) and niobium (Nb) contents were investigated. Experimental results pointed out that the filler wire Ti content required to be twice time more than the amount expected in the deposited metal. This was due to the low Ti transfer ratio during arc welding. Moreover, Ti increased the wetting angle and promoted penetration. It was supposed that Ti affected the weld pool surface tension what led to inward Marangoni convection. Columnar to equiaxed grain transiton (CET) was also promoted thanks to the precipitation in the weld pool of Ti rich refractory compounds which act as heterogeneous nucleation sites for equiaxed grains. A minimum 0.3% Ti was required in the filler wire to form a completely equiaxed grain structure in the fusion zone. Niobium in the filler wire did not seem to have any effect on penetration, wetting and grain structure of the fusion zone.
Several characteristic waves detected by seismographs in Antarctic stations have been recognized as originating from the physical interaction between the solid earth and the atmosphere-ocean-cryosphere system surrounding the Antarctic and may be used as a proxy for characterizing ocean wave climate. A Chaparral-type infrasound sensor was installed at Syowa Station (SYO; 39.6E, 69.0S), East Antarctica, in April 2008 during the International Polar Year (IPY2007-2008). Matching data are also available for this time period from the existing broadband seismic recorder located close by. Continuous infrasound data for 2008-2009 include background signals (microbaroms) with a broad peak in the wave period between the values of 4 and 10 s. Signals with the same period are recorded by the broadband seismograph at SYO (microseisms). This period band is identified as double-frequency microseisms/baroms (DFM). The DFM have relatively lower amplitudes during winter. We suggest that this is due to the sea-ice extent around the coast causing a decreased ocean loading effect. In contrast, the single frequency microseisms/baroms with a peak in period between 12 and 30 s are observed under storm conditions, particularly in winter. On the infrasound data, stationary signals are identified with harmonic overtones at a few Hertz to lowermost human audible band, which we suggest is due to local effects such as sea-ice cracking and vibration. Microseism measurements are a useful proxy for characterizing ocean wave climate, complementing other oceanographic and geophysical data. At SYO, continuous monitoring by both broadband seismograph and infrasound contributes to the Federation of Digital Seismographic Networks, the Comprehensive Nuclear-Test-Ban Treaty in the high southern latitudes and the Pan-Antarctic Observations System under the Scientific Committee on Antarctic Research.
Three types of pathways (degradation-recondensation, natural sulphurization and selective preservation) are commonly considered for the formation of kerogen dispersed in sedimentary rocks. A fourth pathway has been recently put forward, however, from studies on Recent marine sediments, the so-called sorptive protection mechanism. This pathway is based on the adsorption of otherwise labile organic compounds onto minerals, thus preventing their diagenetic degradation and promoting their subsequent condensation into kerogen. The main results of the present study are derived from a combination of microscopic and pyrolytic methods applied on a Cenomanian kerogen. They provide (i) evidence, on an ancient material, for a crucial role of the mineral matrix both in organic matter (OM) preservation during kerogen formation and in kerogen stability once formed, (ii) indications that the dominant protective process likely involves physical protection by minerals, resulting from alternation of organic and clay nanolayers of approximately 100 nm in thickness, rather than OM adsorption as molecular monolayers and (iii) observations of the relatively poor stability of an isolated kerogen, contrary to the inertness commonly assumed for fossil macromolecular organic matter.
An efficient numerical method to compute solitary wave solutions to the free surface Euler equations is reported. It is based on the conformal mapping technique combined with an efficient Fourier pseudo-spectral method. The resulting nonlinear equation is solved via the Petviashvili iterative scheme. The computational results are compared to some existing approaches, such as the Tanaka method and Fenton's high-order asymptotic expansion. Several important integral quantities are numerically computed for a large range of amplitudes. The integral representation of the velocity and acceleration fields in the bulk of the fluid is also provided.
An efficient numerical method to compute solitary wave solutions to the free surface Euler equations is reported. It is based on the conformal mapping technique combined with an efficient Fourier pseudo-spectral method. The resulting nonlinear equation is solved via the Petviashvili iterative scheme. The computational results are compared to some existing approaches, such as the Tanaka method and Fenton's high-order asymptotic expansion. Several important integral quantities are numerically computed for a large range of amplitudes. The integral representation of the velocity and acceleration fields in the bulk of the fluid is also provided.
An improved Lozi function with alternate coefficients has been proposed. The modifications in the model allow to remove the holes in the attractor which are not desirable, but appeared in the previous Lozi function; in this way, an everywhere dense attractor can be obtained. Moreover, the strong sensitivity to the type of binarisation (conversion of real values to 0 and 1) has been demonstrated; this conversion to binary numbers is instrumental to apply the NIST tests for randomness. The results have been validated and compared via NIST tests, for the different methods of quantization. Finally, is has been verfied that the multi-random properties of the output signal have been improved thanks to the following strategies : under-sampling of the output signal, and the system order increasing. Keywords. Nonlinear dynamical system, ring-coupled map, Lozi function, NIST tests, discrete-time map, dense chaotic attractor, pseudo random number generator 1 I
The extreme characteristics of long wave run-up are studied in this paper. First we give a brief overview of the existing theory which is mainly based on the hodograph transformation (Carrier & Greenspan, 1958). Then, using numerical simulations, we build on the work of Stefanakis et al. (2011) for an infinite sloping beach and we find that resonant run-up amplification of monochromatic waves is robust to spectral perturbations of the incoming wave and resonant regimes do exist for certain values of the frequency. In the setting of a finite beach attached to a constant depth region, resonance can only be observed when the incoming wavelength is larger than the distance from the undisturbed shoreline to the seaward boundary. Wavefront steepness is also found to play a role in wave run-up, with steeper waves reaching higher run-up values.
Fifty years ago, FitzHugh introduced a phase portrait that became famous for a twofold reason: it captured in a physiological way the qualitative behavior of Hodgkin-Huxley model and it revealed the power of simple dynamical models to unfold complex firing patterns. To date, in spite of the enormous progresses in qualitative and quantitative neural modeling, this phase portrait has remained a core picture of neuronal excitability. Yet, a major difference between the neurophysiology of 1961 and of 2011 is the recognition of the prominent role of calcium channels in firing mechanisms. We show that including this extra current in Hodgkin-Huxley dynamics leads to a revision of FitzHugh-Nagumo phase portrait that affects in a fundamental way the reduced modeling of neural excitability. The revisited model considerably enlarges the modeling power of the original one. In particular, it captures essential electrophysiological signatures that otherwise require non-physiological alteration or considerable complexification of the classical model. As a basic illustration, the new model is shown to highlight a core dynamical mechanism by which calcium channels control the two distinct firing modes of thalamocortical neurons.
This paper studies the excitability properties of a generalized FitzHugh-Nagumo model. The model differs from the classical FitzHugh-Nagumo model in that it accounts for the effect of cooperative gating variables such as activation of calcium currents. Excitability is explored by unfolding a pitchfork bifurcation that is shown to organize five different types of excitability. In addition to the three classical types of neuronal excitability, two novel types are described and distinctly associated to the presence of cooperative variables.
Les tâches d'empan de mémoire de travail sont des tâches dans lesquelles des items doivent être maintenus en mémoire à court terme pendant qu'un traitement concurrent est effectué. Le but de la présente étude était de déterminer si, comme le soutient le modèle de partage temporel des ressources (Barrouillet, Bernardin, & Camos, 2004), les traitements gênent le maintien parce que les deux composantes entrent en compétition pour des processus communs ou plus simplement parce que les stratégies de maintien des items à rappeler sont perturbées par l'intrusion de l'information à traiter simultanément. Quatre-vingt sujets adultes étaient soumis à une tâche d'empan où ils devaient maintenir des lettres en même temps qu'ils devaient juger soit de la parité soit de la position spatiale de nombre présentés successivement à l'écran. Par ailleurs, ces nombres apparaissaient à un rythme régulier et donc prévisible ou bien aléatoire. Conformément à nos attentes, et contrairement à l'hypothèse d'une perturbation des stratégies de maintien, les jugements de parité qui nécessitent des récupérations en mémoire entraînaient de plus faibles empans que la tâche spatiale qui ne requiert qu'une sélection de réponse alors que le rythme de réalisation de la tâche secondaire n'avait pas d'effet sur les empans.
Several characteristic waves detected by seismographs in Antarctic stations have been recognized as originating from the physical interaction between the solid earth and the atmosphere-ocean-cryosphere system surrounding the Antarctic and may be used as a proxy for characterizing ocean wave climate. A Chaparral-type infrasound sensor was installed at Syowa Station (SYO; 39.6E, 69.0S), East Antarctica, in April 2008 during the International Polar Year (IPY2007-2008). Matching data are also available for this time period from the existing broadband seismic recorder located close by. Continuous infrasound data for 2008-2009 include background signals (microbaroms) with a broad peak in the wave period between the values of 4 and 10 s. Signals with the same period are recorded by the broadband seismograph at SYO (microseisms). This period band is identified as double-frequency microseisms/baroms (DFM). The DFM have relatively lower amplitudes during winter. We suggest that this is due to the sea-ice extent around the coast causing a decreased ocean loading effect. In contrast, the single frequency microseisms/baroms with a peak in period between 12 and 30 s are observed under storm conditions, particularly in winter. On the infrasound data, stationary signals are identified with harmonic overtones at a few Hertz to lowermost human audible band, which we suggest is due to local effects such as sea-ice cracking and vibration. Microseism measurements are a useful proxy for characterizing ocean wave climate, complementing other oceanographic and geophysical data. At SYO, continuous monitoring by both broadband seismograph and infrasound contributes to the Federation of Digital Seismographic Networks, the Comprehensive Nuclear-Test-Ban Treaty in the high southern latitudes and the Pan-Antarctic Observations System under the Scientific Committee on Antarctic Research.
Three types of pathways (degradation-recondensation, natural sulphurization and selective preservation) are commonly considered for the formation of kerogen dispersed in sedimentary rocks. A fourth pathway has been recently put forward, however, from studies on Recent marine sediments, the so-called sorptive protection mechanism. This pathway is based on the adsorption of otherwise labile organic compounds onto minerals, thus preventing their diagenetic degradation and promoting their subsequent condensation into kerogen. The main results of the present study are derived from a combination of microscopic and pyrolytic methods applied on a Cenomanian kerogen. They provide (i) evidence, on an ancient material, for a crucial role of the mineral matrix both in organic matter (OM) preservation during kerogen formation and in kerogen stability once formed, (ii) indications that the dominant protective process likely involves physical protection by minerals, resulting from alternation of organic and clay nanolayers of approximately 100 nm in thickness, rather than OM adsorption as molecular monolayers and (iii) observations of the relatively poor stability of an isolated kerogen, contrary to the inertness commonly assumed for fossil macromolecular organic matter.
An efficient numerical method to compute solitary wave solutions to the free surface Euler equations is reported. It is based on the conformal mapping technique combined with an efficient Fourier pseudo-spectral method. The resulting nonlinear equation is solved via the Petviashvili iterative scheme. The computational results are compared to some existing approaches, such as the Tanaka method and Fenton's high-order asymptotic expansion. Several important integral quantities are numerically computed for a large range of amplitudes. The integral representation of the velocity and acceleration fields in the bulk of the fluid is also provided.
Despite the existence of many studies about the different aspects of fixation in creativity and design reasoning, the underlying mechanisms of fixation, i.e., the processes that interfere during creative reasoning and lead one to become fixated on a small number of unvaried solutions, remain unclear. In this paper, we propose a theoretical framework to model fixation based on C-K design theory, which states that fixation is characterised as a set of restrictive heuristics activated in creative reasoning. We applied our framework in a set of experiments. We demonstrated how this framework makes sense of the varieties of fixation in design processes. We conclude by proposing three capabilities to understand fixation and overcome it: restrictive heuristics development, inhibitory control and expansion.
In France, one of ten recently-hired workers works in retailing. The literature provides evidence about the screening criteria used to fill low-wage vacancies in stores. However, neither the stage when criteria matter nor the forefront role of information channels (direct applications, word-of-mouth, employment agency and job ads) has been well explored. Drawing on 35 interviews conducted in 2010-2011, with actors involved in recruitment activities and with recently-hired workers in large stores in Greater Paris, this article explores the initial interaction between job seekers and recruiters. It is argued that the screening criteria vary according to the way employers received information about applicants and first interact with them (by mail, phone or face-to-face). This contribution highlights the importance of walk-in applications, which prioritize selection based on residence, appearances and availability. Changes in the first interaction impact the whole selection process and may change the profile of the workers hired.
This article examines the role of Internet based labour market intermediaries in coordinating job seeker/employee interactions. A twofold analysis examines on the one hand the matchmaking tools determining applicants' access to job ads, and on the other, the content of ads posted on the web. Observations reveal that the information available to applicants is subject to a high degree of filtering achieved through the use of pre-defined lists, keywords or more frequently, input fields. A comparative analysis of job offers posted on the Internet with those posted in newspapers shows that search engine toolkits have a considerable impact on ad content which is generally more standardized and quantified in the former than in the latter. Furthermore, a comparison between French and British ads demonstrates that the institutional context influences the actions taken by job boards. In contrast to Great Britain, France more frequently uses matching markers aimed at selecting applicants than those providing detailed information on the job offer. Today, French job boards thus contribute in weakening applicants' position on labour markets.
An experimental approach is presented in order to study the evolution of the spreading of a macro-drop of liquid metal. The objective of this work is to supply qualitative and quantitative information during the deposit of liquid metal in static pulsed Gas Metal Arc Welding (P-GMAW). The experimental results are analyzed in the light of dimensionless numbers in order to identify the involved physical mecanisms and appreciate the heat and mass e ects on the behavior of such a macro-drop.
Several compositions of metal cored filler wire were manufactured to define the best welding conditions for homogeneous welding, by Gas Metal Arc Welding (GMAW) process, of a modified AISI 444 ferritic stainless steel dedicated to automotive exhaust manifold applications. The patented grade is know under APERAM trade name K44X and has been developed to present improved high temperature fatigue properties. All filler wires investigated contained 19%Cr and 1.8%Mo, equivalent to the base metal K44X chemistry, but various titanium and niobium contents. Chemical analyses and microstructural observations of fusion zones revealed the need of a minimum Ti content of 0.15% to obtain a completely equiaxed grain structure. This structure conferred on the fusion zone a good ductility even in the as-welded state at room temperature. Unfortunately, titanium additions decreased the oxidation resistance at 950°C if no significant Nb complementary alloying was made. The combined high Ti and Nb additions made it possible to obtain for the welded structure, after optimized heat treatment, high temperature tensile strengths and ductility for the fusion zones and assemblies, rather close to those of the base metal. 950°C aging heat treatment was necessary to restore significantly the ductility of the as welded structure. Both fusion zone and base metal presented rather homogenized properties. Finally, with the optimized composition of the cored filler wire - 0.3 Ti minimum (i.e. 0.15% in the fusion zone) and high Nb complementary additions, the properties, including the thermal fatigue strength, of the K44X assemblies are excellent.
Seven compositions of metal cored filler wires for Gas Metal Arc Welding (GMAW), containing the same weight percent of chromium (Cr) and molybdenum (Mo) as 444 steel, but with different titanium (Ti) and niobium (Nb) contents were investigated. Experimental results pointed out that the filler wire Ti content required to be twice time more than the amount expected in the deposited metal. This was due to the low Ti transfer ratio during arc welding. Moreover, Ti increased the wetting angle and promoted penetration. It was supposed that Ti affected the weld pool surface tension what led to inward Marangoni convection. Columnar to equiaxed grain transiton (CET) was also promoted thanks to the precipitation in the weld pool of Ti rich refractory compounds which act as heterogeneous nucleation sites for equiaxed grains. A minimum 0.3% Ti was required in the filler wire to form a completely equiaxed grain structure in the fusion zone. Niobium in the filler wire did not seem to have any effect on penetration, wetting and grain structure of the fusion zone.
The development of endocavitary dual-mode probes is essential for the accurate treatment of many deep seated cancers which require a high imaging resolution and the capacity to selectively treat focal areas in the region of interest. The MULTIP project is aimed at using state-of-art piezoelectric technologies to design dual-mode ultrasonic probes for cancer-foci treatment and monitoring. In order to allow an efficient surgery planning, the technical study has been accompanied by a volume processing study permitting the design of the ultrasonic imaging/therapy process based on high-resolutionhigh-quality MRI images. Several prototypes were designed based on a simulation study and implemented: 1) two successive wide-band dual-mode transducer allowing imaging at high resolution (6 MHz) on a wide field of view, and therapy at 3 MHz with a good transduction efficiency (48% and 70%); 2) a therapy-only transducer matrix adapted to the desired curvature with a high transduction efficiency (70%). Finally, a registration study of MRI volumes on ultrasound volumes has shown that, because of the texture of the ultrasound images, it is more efficient to search at registering the surfaces of the volumes once they have been segmented in each modality, rather than trying to register the two data volumes directly.
BACKGROUND: Preterm birth is a global problem in Perinatal and infant Health. Currently is gaining a growing attention. Rates of preterm birth have increased in most countries, producing a dramatic impact on public health. Factors of diverse nature have been associated to these trends.In Chile, preterm birth has increased since 90. Simultaneously, the advanced demographic transition has modified the characteristics of woman population related to maternity.The principal objective of this study is to analyze some sociodemographic characteristics of the maternal population over time, and their possible association to rates of preterm birth. The second aim is to identify groups of mothers at high risk of having a preterm child. METHODS: This population-based study examined all liveborn singletons in Chile from 1991 to 2008; divided in three periods. Preterm birth rates were measured as % births <37 weeks of gestation.Logistic regression assessed the risk of preterm birth associated with mother's age, parity, and marital status, expressed as crude and adjusted odds ratios. RESULTS: Over time, rates of preterm birth increased in overall population, especially during the third period (2001--2008). In the same time, characteristics of maternal population changed: significant increase of extreme reproductive ages, significant decrease in parity and increase in mothers living without a partner.Risk of preterm birth remained higher in groups of mothers: < 18 and >38 years of age; without a partner; primiparas and grandmultiparas. However, global increase in preterm birth was not explained by the modification of socio demographics characteristics of maternal population. CONCLUSIONS: Some socio demographic characteristics remained associated with preterm birth over time. These associations allowed identifying five groups of mothers at higher risk to have a preterm child in the population.Increase in overall preterm birth affected all women, even those considered at "low sociodemographic risk" and the contribution of more recent period (2001--2008) to this increase is greater.Then, studied factors couldn't explain the increase in preterm birth. Further research will have to consider other factors affecting maternal population that could explain the observed trend of preterm birth.
Holoprosencephaly (HPE) is a common congenital defect that results from failed or incomplete forebrain cleavage. HPE is characterized by a wide clinical spectrum, with inter- and intrafamilial variability. This heterogeneity is not well understood and it has been suggested that HPE involves a combination of multiple gene mutations. In this model, several mutated alleles or modifying factors are presumed to act in synergy to cause and determine the severity of HPE. This could explain the various clinical phenotypes. Screening for HPE-associated genes in humans suggests the involvement of NODAL or SHH signaling, or both. To test this multigenic hypothesis, we investigated the effects of chemical inhibition of these two main HPE signaling pathways in a chick embryo model. SB-505124, a selective inhibitor of transforming growth factor-B type I receptors was used to inhibit the NODAL pathway. Cyclopamine was used to inhibit the SHH pathway. We report that both inhibitors caused HPE-like defects that were dependent on the drug concentration and on the developmental stage at the time of treatment. We also investigated double inhibition of NODAL and SHH pathways from the onset of gastrulation by using subthreshold inhibitor concentrations. The inhibitors of the NODAL and SHH pathways, even at low concentration, acted synergistically to promote an HPE-like phenotype. These findings support the view that genetic heterogeneity is important in the etiology of HPE and may contribute to the phenotypic variability.
Présentation du calcul de la distance intertextuelle et de deux méthodes de classification (classification hiérarchique ascendante, analyse arborée). Caractérisation du vocabulaire spécifique des différentes classes. Application à un groupe d'entretiens sur le confort électrique.
We consider supervised learning problems within the positive-definite kernel framework, such as kernel ridge regression, kernel logistic regression or the support vector machine. With kernels leading to infinite-dimensional feature spaces, a common practical limiting difficulty is the necessity of computing the kernel matrix, which most frequently leads to algorithms with running time at least quadratic in the number of observations n, i.e., O(n^2). Low-rank approximations of the kernel matrix are often considered as they allow the reduction of running time complexities to O(p^2 n), where p is the rank of the approximation. The practicality of such methods thus depends on the required rank p. In this paper, we show that in the context of kernel ridge regression, for approximations based on a random subset of columns of the original kernel matrix, the rank p may be chosen to be linear in the degrees of freedom associated with the problem, a quantity which is classically used in the statistical analysis of such methods, and is often seen as the implicit number of parameters of non-parametric estimators. This result enables simple algorithms that have sub-quadratic running time complexity, but provably exhibit the same predictive performance than existing algorithms, for any given problem instance, and not only for worst-case situations.
To take account of the uncertainties introduced on the soft magnetic materials properties (magnetic behavior law, iron losses) during the manufacturing process, the present work deals with the stochastic modeling of the magnetic behavior law B-H and iron losses of claw pole stator generator. Twenty eight (28) samples of slinky stator (SS) coming from the same production chain have been investigated. The used approaches are similar to those used in mechanics. The accuracy of existing anhysteretic models has been tested first using cross validation techniques. The well known iron loss separation model has been implemented to take into account the variability of the losses. Then, the Multivariate Gaussian distribution is chosen to model the variability and dependencies between identified parameters, for both behavior law and iron loss models. The developed stochastic models allow predicting a 98% confidence interval for the considered samples
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