%0 Journal Article
%T Effect of Confinement on Capillary Phase Transition in Granular Aggregates
%+ Department of Civil and Environmental Engineering [Cambridge] (CEE)
%+ Department of Physics [MIT Cambridge]
%+ Institut für Quantenoptik [Hannover] (IQ)
%+ Multiscale Material Science for Energy and Environment (MSE 2)
%+ Physique et Mécanique des Milieux Divisés (PMMD)
%+ MIT Department of Civil and Environmental Engineering (CEE)
%+ Centre Interdisciplinaire de Nanoscience de Marseille (CINaM)
%A Monfared, Siavash
%A Zhou, Tingtao
%A Andrade, José
%A Ioannidou, Katerina
%A Radjai, Farhang
%A Ulm, Franz
%A Pellenq, Roland, J. M.
%< avec comité de lecture
%@ 0031-9007
%J Physical Review Letters
%I American Physical Society
%V 125
%N 25
%P 255501
%8 2020-12-25
%D 2020
%R 10.1103/PhysRevLett.125.255501
%Z Physics [physics]/Physics [physics]Journal articles
%X Using a 3D mean-field lattice-gas model, we analyze the effect of confinement on the nature of capillary phase transition in granular aggregates with varying disorder and their inverse porous structures obtained by interchanging particles and pores. Surprisingly, the confinement effects are found to be much less pronounced in granular aggregates as opposed to porous structures. We show that this discrepancy can be understood in terms of the surface-surface correlation length with a connected path through the fluid domain, suggesting that this length captures the true degree of confinement. We also find that the liquid-gas phase transition in these porous materials is of second order nature near capillary critical temperature, which is shown to represent a true critical temperature, i.e., independent of the degree of disorder and the nature of the solid matrix, discrete or continuous. The critical exponents estimated here from finite-size scaling analysis suggest that this transition belongs to the 3D random field Ising model universality class as hypothesized by F. Brochard and P.G. de Gennes, with the underlying random fields induced by local disorder in fluid-solid interactions.
%G English
%2 https://hal.science/hal-03100486/document
%2 https://hal.science/hal-03100486/file/Ioannidou_al_PRL_2020.pdf
%L hal-03100486
%U https://hal.science/hal-03100486
%~ CNRS
%~ UNIV-AMU
%~ LMGC
%~ CINAM
%~ MIPS
%~ UNIV-MONTPELLIER
%~ UM-2015-2021