%0 Journal Article %T High temperature piezoelectric properties of flux-grown α-GeO 2 single crystal %+ Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM) %+ Laboratoire Charles Coulomb (L2C) %+ Cristaux massifs (NEEL - CrisMass) %+ Optique et Matériaux (NEEL - OPTIMA) %A Papet, Philippe %A Bah, Micka %A Haidoux, Abel %A Ruffle, Benoit %A Ménaert, Bertrand %A Pena Revellez, Alexandra %A Debray, Jérôme %A Armand, Pascale %< avec comité de lecture %@ 0021-8979 %J Journal of Applied Physics %I American Institute of Physics %V 126 %N 14 %P 144102 %8 2019-10-14 %D 2019 %R 10.1063/1.5116026 %Z Chemical Sciences/Material chemistry %Z Chemical Sciences/Inorganic chemistry %Z Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Journal articles %X The temperature-dependence of the piezoelectric properties of trigonal -GeO2 single-crystals obtained by the high-temperature flux method was measured by the resonance technique of the electrical impedance in the 20°C-600°C range. To approach the values of the two independent piezoelectric coefficients d11 and d14, we first measured as a function of temperature the elastic coefficients S11, S14 and S66 and the dielectric permittivity 11 which are involved in the coupling coefficient k of both the thickness shear mode and the transverse mode. A Y-cut plate with a simple +45°-rotation ((YXtwl) +45°/0°/0°) was used to measure the coupling coefficient of the thickness shear mode, and two X-turned plates ((XYtwl) +45°/0°/0° and (XYtwl)-45°/0°/0°) were prepared to characterize the coupling coefficient of two transverse modes. From the whole experimental measurements, the piezoelectric coefficients of -GeO2 were calculated up to 600 °C. They show that this crystal is one of the most efficient in regard of the -quartz-like family at room temperature, and that its thermal comportment retains large piezoelectric properties up to 600°C. %G English %2 https://hal.science/hal-02316058/document %2 https://hal.science/hal-02316058/file/JAP19-AR-03725.pdf %L hal-02316058 %U https://hal.science/hal-02316058 %~ UGA %~ CNRS %~ ENSC-MONTPELLIER %~ INPG %~ NEEL %~ ICG %~ L2C %~ INC-CNRS %~ NEEL-OPTIMA %~ NEEL-CRISMASS %~ MIPS %~ CHIMIE %~ UNIV-MONTPELLIER %~ TEST-HALCNRS %~ UGA-COMUE %~ ANR %~ UM-2015-2021 %~ NEEL-TECHNO