%0 Journal Article %T Van der Waals epitaxy of two-dimensional single-layer h-BN on graphite by molecular beam epitaxy: Electronic properties and band structure %+ CELLS ALBA synchroton = ALBA Synchrotron (CELLS ALBA) %+ Centre de Nanosciences et de Nanotechnologies [Marcoussis] (C2N) %+ Synchrotron SOLEIL (SSOLEIL) %+ Laboratoire Charles Coulomb (L2C) %+ School of Physics and Astronomy [Nottingham] %+ Laboratoire de photonique et de nanostructures (LPN) %A Pierucci, Deborah %A Zribi, Jihene %A Henck, Hugo %A Chaste, Julien %A Silly, Mathieu G. %A Bertran, François %A Le Fevre, P. %A Gil, Bernard %A Summerfeld, Alex %A Beton, Peter %A Novikov, Sergei %A Cassabois, Guillaume %A Rault, Julien %A Ouerghi, Abdelkarim %< avec comité de lecture %Z L2C:18-118 %@ 0003-6951 %J Applied Physics Letters %I American Institute of Physics %V 112 %N 25 %P 253102 %8 2018 %D 2018 %R 10.1063/1.5029220 %K Boron nitride %Z Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Journal articles %X We report on the controlled growth of h-BN/graphite by means of molecular beam epitaxy. X-Ray photoelectron spectroscopy suggests the presence of an interface without any reaction or intermixing, while the angle resolved photoemission spectroscopy (ARPES) measurements show that the h-BN layers are epitaxially aligned with graphite. A well-defined band structure is revealed by ARPES measurements, reflecting the high quality of the h-BN films. The measured valence band maximum located at 2.8 eV below the Fermi level reveals the presence of undoped h-BN films (band gap similar to 6 eV). These results demonstrate that, although only weak van der Waals interactions are present between h-BN and graphite, a long range ordering of h-BN can be obtained even on polycrystalline graphite via van der Waals epitaxy, offering the prospect of large area, single layer h-BN %G English %Z LABEX GANEX %2 https://hal.science/hal-01863526/document %2 https://hal.science/hal-01863526/file/Van%20der%20Waals%20epitaxy_1.5029220.pdf %L hal-01863526 %U https://hal.science/hal-01863526 %~ CNRS %~ UNIV-PSUD %~ L2C %~ UNIV-PARIS-SACLAY %~ UNIV-PSUD-SACLAY %~ SYNCHROTRON-SOLEIL %~ MIPS %~ UNIV-MONTPELLIER %~ UP-SCIENCES %~ ANR %~ GS-PHYSIQUE %~ INSTITUT-SCIENCES-LUMIERE %~ UM-2015-2021 %~ C2N