%0 Journal Article %T The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks %+ Institut des Biomolécules Max Mousseron [Pôle Chimie Balard] (IBMM) %A Riss-Yaw, B. %A Clavel, C. %A Laurent, Ph. %A Coutrot, F. %< avec comité de lecture %@ 1359-7345 %J Chemical Communications %I Royal Society of Chemistry %V 53 %N 79 %P 10874 - 10877 %8 2017 %D 2017 %R 10.1039/c7cc06598a %M 28926040 %K rotaxane %K slippage %K N-hydroxysuccinimide %K DB24C8 %Z Chemical Sciences/Organic chemistryJournal articles %X A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain anammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread. %G English %L hal-01616749 %U https://hal.science/hal-01616749 %~ CNRS %~ ENSC-MONTPELLIER %~ IBMM %~ INC-CNRS %~ CHIMIE %~ UNIV-MONTPELLIER %~ UM-2015-2021 %~ TEST2-HALCNRS