The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2017

The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

Résumé

A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain anammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread.

Domaines

Chimie organique
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Dates et versions

hal-01616749 , version 1 (14-10-2017)

Identifiants

Citer

B. Riss-Yaw, C. Clavel, Ph. Laurent, F. Coutrot. The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks. Chemical Communications, 2017, 53 (79), pp.10874 - 10877. ⟨10.1039/c7cc06598a⟩. ⟨hal-01616749⟩
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