Synergistic Effect of Small Molecules on Large-Scale Structure of Simplified Industrial Nanocomposites

Dafne Musino (1) , Anne-Caroline Genix (1) , Caroline Fayolle (2) , Aurelie Papon (2) , Laurent Guy (2) , Natalia Meissner , Radoslaw Kozak , Pawel Weda , Thomas Bizien (3) , Thomas Chaussee (2) , Julian Oberdisse (1)

1 L2C - Laboratoire Charles Coulomb
2 Solvay Silica
3 SSOLEIL - Synchrotron SOLEIL

The microstructure of polymer nanocomposites made with disordered silica filler (Zeosil(R) 1165MP) of industrial relevance and various coating agents is quantitatively analyzed using a combination of SAXS, TEM, and a recently developed structural model. The polymer matrix is formed by an end-functionalized styrene-butadiene statistical copolymer capable of covalent grafting on the silica nanoparticles. The effect of the coating agents with different alkyl chain length (C8, C12, and C18) on filler structure quantified in terms of aggregate formation, for different concentrations (up to 8%wt with respect to silica), and the effect of a commonly added catalyzer, DPG, are studied using the structural model. As a result we show that a strongly synergetic effect of both DPG and coating agent exist. Our findings open the road to a fundamental understanding and rational design of model and industrial nanocomposite formulation with optimized coating agents.

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Dafne Musino, Anne-Caroline Genix, Caroline Fayolle, Aurelie Papon, Laurent Guy, et al.. Synergistic Effect of Small Molecules on Large-Scale Structure of Simplified Industrial Nanocomposites. Macromolecules, 2017, 50 (13), pp.5138-5145. ⟨10.1021/acs.macromol.7b00954⟩. ⟨hal-01580193⟩