%0 Journal Article %T Direct observation of the band structure in bulk hexagonal boron nitride %+ Laboratoire de photonique et de nanostructures (LPN) %+ Laboratoire des Solides Irradiés - Irradiated Solids Laboratory (LSI) %+ Synchrotron SOLEIL (SSOLEIL) %+ Laboratoire Charles Coulomb (L2C) %+ Service de physique de l'état condensé (SPEC - UMR3680) %A Henck, Hugo %A Pierucci, Debora %A Fugallo, Giorgia %A Avila, Jose %A Cassabois, Guillaume %A Dappe, Yannick J. %A Silly, Mathieu G. %A Chen, Chaoyu %A Gil, Bernard %A Gatti, Matteo %A Sottile, Francesco %A Sirotti, Fausto %A Asensio, Maria C. %A Ouerghi, Abdelkarim %< avec comité de lecture %Z L2C:17-016 %@ 2469-9950 %J Physical Review B %I American Physical Society %V 95 %N 8 %P 085410 %8 2017-02-08 %D 2017 %R 10.1103/PhysRevB.95.085410 %Z Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Journal articles %X A promising route towards nanodevice applications relies on the association of graphene and transition metal dichalcogenides with hexagonal boron nitride (h-BN). Due to its insulating nature, h-BN has emerged as a natural substrate and gate dielectric for graphene-based electronic devices. However, some fundamental properties of bulk h-BN remain obscure. For example, the band structure and the position of the Fermi level have not been experimentally resolved. Here, we report a direct observation of parabolic dispersions of h-BN crystals using high-resolution angle-resolved photoemission spectroscopy (ARPES). We find that h-BN exfoliation on epitaxial graphene enables overcoming the technical difficulties of using ARPES with insulating materials. We show trigonal warping of the intensity maps at constant energy. The valence-band maxima are located around the K points, 2.5 eV below the Fermi level, thus confirming the residual p-type character of typical h-BN. %G English %L hal-01487020 %U https://hal.science/hal-01487020 %~ CEA %~ X %~ CNRS %~ X-LSI %~ X-DEP %~ X-DEP-PHYS %~ L2C %~ IRAMIS-SPEC %~ CEA-UPSAY %~ UNIV-PARIS-SACLAY %~ CEA-UPSAY-SACLAY %~ X-SACLAY %~ SYNCHROTRON-SOLEIL %~ MIPS %~ UNIV-MONTPELLIER %~ TEST-HALCNRS %~ ANR %~ GS-ENGINEERING %~ IRAMIS %~ GS-PHYSIQUE %~ INSTITUT-SCIENCES-LUMIERE %~ UM-2015-2021