%0 Journal Article %T Raman Signatures of Single Layer Graphene Dispersed in Degassed Water, “‘Eau de Graphene”’ %+ Centre de Recherche Paul Pascal (CRPP) %+ Laboratoire Charles Coulomb (L2C) %A Bepete, George %A Pénicaud, Alain %A Drummond, Carlos %A Anglaret, Eric %< avec comité de lecture %Z L2C:16-197 - CRPP 116-12329 %@ 1932-7447 %J Journal of Physical Chemistry C %I American Chemical Society %V 120 %P http://dx.doi.org/10.1021/acs.jpcc.6b07288 %8 2016-12-01 %D 2016 %R 10.1021/acs.jpcc.6b07288 %Z Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] %Z Physics [physics]/Condensed Matter [cond-mat]/Soft Condensed Matter [cond-mat.soft]Journal articles %X We report a detailed Raman study of single layergraphene dispersed in degassed water without additives (SLGiw), so-called “‘eau de graphene”’ (EdG).23 The most characteristic signature of SLGiw is a narrow (28 ± 2 cm−1) and symmetric 2D band. The intensity of the D band is dominated by the contribution of sp3 defects due to slight functionalization of the basal-planes. The density of defects is estimated in the range 200-650 ppm by studying thin films prepared from EdG. These defects can be fully and easily cured by annealing the films at 800 °C. The position of the G and 2D bands, blue-shifted with respect to pristine SLG, are assigned to moderate biaxial compressive strain (≈0.09 ± 0.02%) and likely weak n doping (<4 × 1012 electrons/cm2) of SLGiw. %G English %L hal-01407045 %U https://hal.science/hal-01407045 %~ CNRS %~ CRPP %~ L2C %~ INC-CNRS %~ MIPS %~ UNIV-MONTPELLIER %~ UM-2015-2021 %~ TEST2-HALCNRS