%0 Conference Paper %F Oral %T Unraveling the bandgap nature in hexagonal boron nitride %+ Laboratoire Charles Coulomb (L2C) %A Cassabois, Guillaume %F Invité %< sans comité de lecture %Z L2C:16-018 %B UK Nitrides Consortium winter conference %C Cambridge, United Kingdom %8 2016-01-06 %D 2016 %Z Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Conference papers %X I will discuss our recent experiments by two-photon spectroscopy demonstrating that hBN is an indirect bandgap material. I will show that the optical properties of hBN are profoundly determined by phonon-assisted transitions involving either virtual or real excitonic states. I will present our measurements of the exciton binding energy by two-photon excitation, leading to the estimation of 6.08 eV for the single-particle bandgap in hBN. %G English %L hal-01281937 %U https://hal.science/hal-01281937 %~ CNRS %~ L2C %~ MIPS %~ UNIV-MONTPELLIER %~ UM-2015-2021