%0 Conference Paper %F Oral %T Optical properties of hexagonal boron nitride %+ Laboratoire Charles Coulomb (L2C) %A Cassabois, Guillaume %A Valvin, Pierre %A Gil, Bernard %F Invité %< sans comité de lecture %Z L2C:15-258 %B 11th International Conference on Nitride Semiconductors (ICNS11) %C Beijing, China %8 2015-08-31 %D 2015 %Z Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Conference papers %X In this paper, I will review our recent results demonstrating that hBN has an indirect bandgap at 5.9 eV. I will show that the optical properties of hBN are profoundly determined by phonon-assisted transitions with a mirror symmetry between emission and absorption around the indirect exciton at 5.9 eV (Figure 1). I will provide a comprehensive analysis of the emission spectrum in the deep ultraviolet in terms of phonon-assisted transitions involving either virtual or real excitonic states, the latter being provided by structural defects. I will finally point out the complex relaxation dynamics of the quantum gas formed by the reservoir of indirect excitons. %G English %L hal-01281931 %U https://hal.science/hal-01281931 %~ CNRS %~ L2C %~ MIPS %~ UNIV-MONTPELLIER %~ UM-2015-2021