Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries

J. Monnier (1) , H. Chen (1) , Suzanne Joiret (2) , J. Bourgon (1) , M. Latroche (1)

1 ICMPE - Institut de Chimie et des Matériaux Paris-Est
2 LISE - Laboratoire Interfaces et Systèmes Electrochimiques

To improve the performances of Nickel-Metal Hydride batteries, an important step is the understanding of the corrosion processes that take place in the electrode material. In particular, the present study focuses for the first time on the model (La, Mg)2Ni7 system. The calendar corrosion in 8.7 M KOH medium was investigated from 6 h to 16 weeks immersion. By a unique combination of structural and elemental characterisations, the corrosion products are evidenced in those systems. In particular, we demonstrate that Ni and Mg combine in a pseudo-binary hydroxide Mg1−xNix(OH)2 whereas La corrodes into nanoporous La(OH)3 needles with inner hollow nanochannels.

Mots clés: Corrosion; Ni-MH batteries; Raman micro spectroscopy; TEM; Combination of techniques

Domaines: Autre

J. Monnier, H. Chen, Suzanne Joiret, J. Bourgon, M. Latroche. Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries. Journal of Power Sources, 2014, 266, pp.162-169. ⟨10.1016/j.jpowsour.2014.05.008⟩. ⟨hal-01025697⟩