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Article Dans Une Revue European Journal of Organic Chemistry Année : 2014

Synthesis of Unnatural Phosphonosugar Analogues.

Résumé

The first synthesis of new cyclic phosphonates (phostones), analogues of pentafuranoses containing a phosphorus atom in place of the anomeric carbon in the deoxyribose and deoxyxylose series, is described. Two methods, of respectively six and seven steps, were developed in parallel, and each gave the racemic phosphonosugars in good yields. Compounds analogous to the alpha and beta anomers were isolated and fully characterized by NMR spectroscopy.

Dates et versions

hal-01004217 , version 1 (11-06-2014)

Identifiants

Citer

Bénédicte Dayde, Claire Pierra, Gilles Gosselin, Dominique Surleraux, Amadou Tidjani Ilagouma, et al.. Synthesis of Unnatural Phosphonosugar Analogues.. European Journal of Organic Chemistry, 2014, 2014 (6), pp.1333-1337. ⟨10.1002/ejoc.201301543⟩. ⟨hal-01004217⟩
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