Effects of the Amount of Fillers and of the Crosslink Density on the Mechanical Behavior of Carbon-Black Filled Styrene Butadiene Rubbers

Yannick Merckel (1) , Julie Diani (2) , Mathias Brieu (1) , Julien Caillard (3)

1 LML - Laboratoire de Mécanique de Lille - FRE 3723
2 PIMM - Laboratoire Procédés et Ingénierie en Mécanique et Matériaux
3 Centre de Technologie de Ladoux

Several carbon-black filled styrene-butadiene rubbers are subjected to monotonic uniaxial tension tests in order to investi-gate the effects of the amount of fillers and of the crosslink density on their mechanical properties. The Young modulus, the volume changes associated with material damage and the stretch to failure are extracted and discussed. Results compare well to the literature results when exist and quantitative analysis are proposed when possible. Results show that filled rubbers are not incompressible when submitted to uniaxial tension tests and their volume changes are strongly dependent of the amount of fillers but are unaffected by the crosslink density. The latter shows strong impact on the filled rubbers stretch to failure but more interestingly this impact is com-parable to what is encountered in unfilled rubbers. The stretch to failure is improved by the addition of fillers with an optimum for material filled around 30 phr.

Mots clés: Rubber; properties and characterization; mechanical properties; elastomers; crosslinking

Domaines: Matériaux; Mécanique [physics.med-ph]

Yannick Merckel, Julie Diani, Mathias Brieu, Julien Caillard. Effects of the Amount of Fillers and of the Crosslink Density on the Mechanical Behavior of Carbon-Black Filled Styrene Butadiene Rubbers. Journal of Applied Polymer Science, 2013, 129, pp.2086-2091. ⟨10.1002/app.38925⟩. ⟨hal-00996697⟩