High-pressure phase transformations, pressure-induced amorphization, and polyamorphic transition of the clathrate Rb6.15Si46
Résumé
The type-I clathrate Rb6.15Si46 with partly empty cage sites has been studied up to 36 GPa using Raman spectroscopy, synchrotron x-ray diffraction in diamond-anvil cells, and ab initio total-energy and lattice-dynamics calculations. A first phase transition is observed at 13±1 GPa and a "volume collapse" transition within the clathrate structure is then observed at 24±1 GPa. Pressure-induced amorphization into a high-density amorphous (HDA) state occurs above P=33±1 GPa. The HDA form transforms into a low-density amorphous polymorph during decompression. During the compression study using angle dispersive synchrotron x-ray diffraction techniques we measured bulk modulus parameters for rocksalt-structured TaO, included adventitiously in the clathrate sample [K0=293(3) GPa and K′0=5.4(3)].
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2009_Machon_PRB79_High-pressure_phase_transformations_pressure-induced_amorphization_and_polyamorphic_transition_of_the_clathrate_Rb6.15Si46.pdf (901.18 Ko)
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