3d and 4d coordination complexes and coordination polymers involving electroactive tetrathiafulvalene containing ligands

Fabrice Pointillart (1) , Stéphane Golhen (1) , Olivier Cador (1) , Lahcène Ouahab (1)

1 ISCR - Institut des Sciences Chimiques de Rennes

The "through bond" approach has been recently developed to increase the interaction between the mobile π and localized d electrons in multifunctional molecular materials involving tetrathiafulvalene-based ligands. This article reviews the 3d and 4d coordination complexes and polymers elaborated from a library of tetrathiafulvalene derivatives containing ligands obtained recently in our group. The different synthetic ways of the complexes are highlighted as well as their chemical and physical properties.

Mots clés: Coordination complexes; Coordination polymers; Electroactive ligands; Tetrathiafulvalene

Domaines: Catalyse

Fabrice Pointillart, Stéphane Golhen, Olivier Cador, Lahcène Ouahab. 3d and 4d coordination complexes and coordination polymers involving electroactive tetrathiafulvalene containing ligands. Comptes Rendus. Chimie, 2013, 16 (7), pp.679-687. ⟨10.1016/j.crci.2012.11.016⟩. ⟨hal-00879552⟩