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| HAL : hal-00726379, version 1 |
| DOI : 10.1021/ja305200h |
| Fiche détaillée |  Récupérer au format |
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| Journal of the American Chemical Society 134, 29 (2012) 11944-11947 |
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| Quantification of Hydrogen Peroxide during the Low-Temperature Oxidation of Alkanes |
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| Chiheb Bahrini 1Olivier Herbinet 1 |
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| (02/07/2012) |
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| The first reliable quantification of hydrogen peroxide (H2O2) formed during the low-temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near-infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was n-butane, the smallest alkane which has an oxidation behavior close to that of the species present in gasoline and diesel fuels. |
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| 1 : | Laboratoire Réactions et Génie des Procédés (LRGP) |
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CNRS : UPR3349 |
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| 2 : | Physicochimie des processus de combustion et de l'atmosphere (PC2A) |
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CNRS : UMR8522 – Université Lille I - Sciences et technologies |
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| Domaine | : | Chimie/Chimie théorique et/ou physique |
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| hydrogen peroxide – low-temperature oxidation – jet-stirred reactor – combustion |
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| Liste des fichiers attachés à ce document : | ||||||||||
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| hal-00726379, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00726379 | |
| oai:hal.archives-ouvertes.fr:hal-00726379 | |
| Contributeur : Olivier Herbinet | |
| Soumis le : Jeudi 30 Août 2012, 10:52:38 | |
| Dernière modification le : Mercredi 9 Janvier 2013, 09:10:58 | |
