%0 Journal Article
%T Reactivity of Surfaces Determined by Local Electrochemical Triggering: A Bromo-Terminated Self-Assembled Monolayer
%+ Institut méditerranéen d'océanologie (MIO)
%+ Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces (LEPMI )
%+ Physicochimie des Electrolytes, Colloïdes et Sciences Analytiques (PECSA)
%A Nunige, Sandra
%A Cornut, Renaud
%A Hazimeh, Hassan
%A Hauquier, Fanny
%A Lefrou, Christine
%A Combellas, Catherine
%A Kanoufi, Frederic
%< avec comité de lecture
%Z MIO:12-028
%@ 1433-7851
%J Angewandte Chemie International Edition
%I Wiley-VCH Verlag
%V 51
%N 21
%P 5208-5212
%8 2012
%D 2012
%R 10.1002/anie.201201083
%M 22499391
%K kinetics
%K electrochemistry
%K self-assembly
%K surface chemistry
%K TRANSFER RADICAL POLYMERIZATION
%K ELECTRON-TRANSFER
%K REACTION-RATES
%K MICROSCOPY
%K OXYGEN
%K INTERROGATION
%K PLATINUM
%K ALKYNES
%K AZIDES
%K ACID
%Z Chemical Sciences/Material chemistry
%Z Chemical Sciences/Analytical chemistry
%Z Sciences of the Universe [physics]/Ocean, AtmosphereJournal articles
%X Magic ink: The chemical reactivity of a bromo-terminated self-assembled monolayer immobilized on an insulating substrate is quantified from the time evolution of patterns formed during the local reduction of the SAM (see picture; bpy=2,2'-bipyridine). The potential of this lithographic strategy to determine the reactivity of the self-assembled monolayer is described and compared to surface interrogation by electrochemical microscopy.
%G English
%L hal-00709269
%U https://hal.science/hal-00709269
%~ INSU
%~ UNIV-SAVOIE
%~ UPMC
%~ ESPCI
%~ UGA
%~ UNIV-TLN
%~ CNRS
%~ UNIV-GRENOBLE1
%~ UNIV-AMU
%~ INPG
%~ PARISTECH
%~ MIO
%~ OSU-INSTITUT-PYTHEAS
%~ GIP-BE
%~ PECSA
%~ LEPMI
%~ INC-CNRS
%~ PSL
%~ SORBONNE-UNIVERSITE
%~ ESPCI-PSL
%~ USMB-COMUE
%~ MIO-CYBELE
%~ ALLIANCE-SU
%~ TEST2-HALCNRS