Lithium-induced dielectric relaxations in potassium tantalate ceramics

A Tkach (1) , A Almeida (1) , J Agostinho Moreira (1) , A Espinha (1) , M R Chaves (1) , J Perez de La Cruz (2) , P M Vilarinho (3)

1 Faculty of Science
2 INESC-ID - Instituto de Engenharia de Sistemas e Computadores Investigação e Desenvolvimento em Lisboa
3 Department of Ceramics and Glass Engineering

This work reports the effect of lithium doping on the dielectric and polar properties of potassium tantalate. Experimental data were obtained in K1-xLixTaO3 ceramics with x = 0, 0.02, 0.05, and 0.10 by measuring both the dielectric permittivity from 10 2 to 10 8 Hz, and polarization under an a.c. electric field driven at 2.5 Hz, for temperatures from 10 to 300 K. The dielectric permittivity exhibits all the relaxations reported for K1-xLixTaO3 single crystals. Two dielectric relaxations observed at 40-125 K are ascribed to the individual hopping by 90 and 180° of dipoles created by the off-centre Li ions. Another relaxation observed at 100-200 K is related to 180°-flips of Li pairs for x = 0.02 and of polar clusters of interacting Li ions for x = 0.05 and 0.10. Besides that, an additional relaxation not reported before is presented at 135-235 K for x = 0.10 and attributed to 90°-reorientation of Li polar clusters. Both the change from an Arrhenius to a Vogel-Fulcher dependence with increasing lithium content, and the emergence of slim P (E) hysteresis loops around the relaxation temperatures show that the relaxation dynamics in K1-xLixTaO3 can be understood if a crossover from a dipolar glass to a relaxor-like behavior is assumed. Abstract This work reports the effect of lithium doping on the dielectric and polar properties of potassium tantalate. Experimental data were obtained in K 1-x Li x TaO 3 ceramics with x = 0, 0.02, 0.05, and 0.10 by measuring both the dielectric permittivity from 10 2 to 10 8 Hz, and polarization under an a.c. electric field driven at 2.5 Hz, for temperatures from 10 to 300 K. The dielectric permittivity exhibits all the relaxations reported for K 1-x Li x TaO 3 single crystals. Two dielectric relaxations observed at 40-125 K are ascribed to the individual hopping by 90 and 180° of dipoles created by the off-centre Li ions. Another relaxation observed at 100-200 K is related to 180°-flips of Li pairs for x = 0.02 and of polar clusters of interacting Li ions for x = 0.05 and 0.10. Besides that, an additional relaxation not reported before is presented at 135-235 K for x = 0.10 and attributed to 90°-reorientation of Li polar clusters. Both the change from an Arrhenius to a Vogel-Fulcher dependence with increasing lithium content, and the emergence of slim P (E) hysteresis loops around the relaxation temperatures show that the relaxation dynamics in K 1-x Li x TaO 3 can be understood if a crossover from a dipolar glass to a relaxorlike behavior is assumed.

Mots clés: Quantum paraelectricity; Lithium doped potassium tantalate; Dielectric relaxtion properties; Microscopic mechanisms

A Tkach, A Almeida, J Agostinho Moreira, A Espinha, M R Chaves, et al.. Lithium-induced dielectric relaxations in potassium tantalate ceramics. Journal of Physics D: Applied Physics, 2011, 44 (31), pp.315406. ⟨10.1088/0022-3727/44/31/315406⟩. ⟨hal-00642370⟩