Intralamellar structural modifications related to the proton exchanging in KNbO layered phase

M.A. Bizeto , F. Leroux , A.L. Shiguihara , M.L.A. Temperini , O. Sala , V.R.L. Constantino

Basic structural aspects about the layered hexaniobate of KNbO composition and its proton-exchanged form were investigated mainly by spectroscopic techniques. Raman spectra of hydrous KNbO and HKNbO.HO show significant modifications in the 950-800 cm region (Nb-O stretching mode of highly distorted NbO octahedra). The band at 900 cm shifts to 940 cm after the replacement of K ion by proton. Raman spectra of the original materials and the related deuterated samples are similar suggesting that no isotopic effect occurs. Major modifications were observed when HKNbO was dehydrated: the relative intensity of the band at 940 cm decreases and new bands seems to be present at about 860-890 cm. The H ions should be shielded by the hydration sphere what preclude the interaction with the layers. Removing the water molecules, H ions can establish a strong interaction with oxygen atoms, decreasing the bond order of Nb-O linkage. X-ray absorption near edge structure studies performed at Nb K-edge indicate that the niobium coordination number and oxidation state remain identical after the replacement of potassium by proton. From the refinement of the fine structure, it appears that the Nb-Nb coordination shell is divided into two main contributions of about 0.33 and 0.39 nm, and interestingly the population, the number of backscattering atoms is inversed between the two hexaniobate materials.

Mots clés: A. Inorganic compounds; B. Raman spectroscopy; C. X-ray absorption spectroscopy

M.A. Bizeto, F. Leroux, A.L. Shiguihara, M.L.A. Temperini, O. Sala, et al.. Intralamellar structural modifications related to the proton exchanging in KNbO layered phase. Journal of Physics and Chemistry of Solids, 2010, 71 (4), pp.560. ⟨10.1016/j.jpcs.2009.12.036⟩. ⟨hal-00628280⟩