Systematic study of interaction of the neutral form of anilines with undecylcalix[4]resorcinarene derivatives by means of potentiometry - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Supramolecular Chemistry Année : 2010

Systematic study of interaction of the neutral form of anilines with undecylcalix[4]resorcinarene derivatives by means of potentiometry

Jerzy Radecki
  • Fonction : Auteur correspondant
  • PersonId : 904305

Connectez-vous pour contacter l'auteur
Katarzyna Kurzatkowska
  • Fonction : Auteur
  • PersonId : 904307
Magdalena Stobiecka
  • Fonction : Auteur
  • PersonId : 904308
Wim F.A. Dehaen
  • Fonction : Auteur
  • PersonId : 904309
Wim Dehaen
  • Fonction : Auteur
  • PersonId : 876913
Hanna Jadwiga Radecka
  • Fonction : Auteur
  • PersonId : 876914

Résumé

The elucidation of the mechanism of potentiometric signals generation by liquid membrane electrodes incorporating undecylcalix[4]resorcinarene derivatives upon stimulation by uncharged aniline derivatives is the main aim of the research presented. A series of molecules which play the role of host and guests in the molecular recognition process which occurring at the aqueous / organic membrane interface were explored. It was proved that in the conditions where all aniline derivatives exist as uncharged molecules, cationic potentiometric signals were observed for all undecylcalix[4]resorcinarene liquid membrane electrodes. The main parameters crucial for this phenomenon are the acidity / basicity of the hosts as well as the guests. The lipophilicity of the guests plays a secondary role.

Mots clés

Fichier principal
Vignette du fichier
PEER_stage2_10.1080%2F10610278.2010.486437.pdf (1 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-00602598 , version 1 (23-06-2011)

Identifiants

Citer

Jerzy Radecki, Remalakshmy Poduval, Katarzyna Kurzatkowska, Magdalena Stobiecka, Wim F.A. Dehaen, et al.. Systematic study of interaction of the neutral form of anilines with undecylcalix[4]resorcinarene derivatives by means of potentiometry. Supramolecular Chemistry, 2010, 22 (07-08), pp.413-419. ⟨10.1080/10610278.2010.486437⟩. ⟨hal-00602598⟩

Collections

PEER
56 Consultations
104 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More