The effects of operating conditions on the performance of a solid oxide steam electrolyser: a model-based study

Qiong Cai (1) , Eduardo Luna-Ortiz (1) , Claire Adjiman (1) , Nigel Brandon (2)

1 Respiratory Epidemiology and Public Health
2 Energy Futures Lab

To support the development of hydrogen production by high temperature electrolysis using solid oxide electrolysis cells (SOECs), the effects of operating conditions on the performance of the SOECs were investigated using a one-dimensional model of a cathode-supported planar SOEC stack. Among all the operating parameters, temperature is the most influential factor on performance, in both cell voltage and operation mode (i.e. endothermic, thermoneutral and exothermic). Current density is another influential factor, in both cell voltage and operation mode. For the conditions used in this study it is recommended that the SOEC be operated at 1073 K and with an average current density of 10000 A m-2, as this results in the stack operating at almost constant temperature along the cell length. Neither the steam molar fraction at the inlet, nor the steam utilisation factor, have significant influence on the cell voltage of the SOEC but their influence on the temperature distribution cannot be neglected. Changes in the operating parameters of the SOEC can result in a transition between endothermic and exothermic operation modes, calling for careful temperature control. The introduction of air into the anode stream appears to be a promising approach to ensure small temperature variation along the cell.

Mots clés: Physical Sciences

Qiong Cai, Eduardo Luna-Ortiz, Claire Adjiman, Nigel Brandon. The effects of operating conditions on the performance of a solid oxide steam electrolyser: a model-based study. Fuel Cells, 2010, 10 (6), pp.1114. ⟨10.1002/fuce.200900211⟩. ⟨hal-00591285⟩