New Development in Rare Earth Metal Complexes Containing Anionic Bis(imino)pyrrolyl and Bis(phosphanyl)amide Ligands

Peter Roesky (1) , Jelena Jenter (1) , Tianshu Li (1)

1 Institut fur Anorganische Chemie

Rare earth element complexes having the very bulky 2,5-bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl, and the sterically less demanding bis(phosphanyl)amide ligand, (PPh2)2N-, in the coordination sphere are reviewed in this research report. The coordination chemistry, the reactivity, and the catalytic application of the corresponding complexes are discussed.

Mots clés: Physical Sciences

Peter Roesky, Jelena Jenter, Tianshu Li. New Development in Rare Earth Metal Complexes Containing Anionic Bis(imino)pyrrolyl and Bis(phosphanyl)amide Ligands. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2010, 636 (12), pp.2148. ⟨10.1002/zaac.201000169⟩. ⟨hal-00568239⟩