[Sn9HgSn9]6-: An Intermetalloid Zintl Ion with Two Sn9 Connected by Heteroatom
Résumé
The title compound [K([2,2,2]crypt)]12[Sn9]2[Sn9HgSn9] has been obtained by reaction of elemental mercury with the binary phase K4Ge9 in ethylenediamine after addition of [2,2,2]crypt and layering with toluene. The X-ray single crystal analysis shows that the compound consists of two isolated Sn9 clusters and two Sn9-clusters connected by a mercury atom.
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