Reactions of Distibanes with [Fe2(CO)9]: Synthesis, Structure and DFT calculations of [(Et2Sb)4Fe4(CO)14], [(n-Pr2Sb)4Fe3(CO)10], [{(Me3SiCH2)2Sb}4Fe2(CO)6], and [2-(Me2NCH2)C6H4SbFe2(CO)8]

Hans Joachim Breunig (1) , Enno Lork (1) , Ovidiu Moldovan (1) , Ciprian Ionut Rat (2)

1 Institut für Anorganische und Physikalische Chemie
2 Faculty of Chemistry and Chemical Engineering

Syntheses of [(Et2Sb)4Fe4(CO)14] (1), [(n-Pr2Sb)4Fe3(CO)10] (2), [{(Me3SiCH2)2Sb}4Fe2(CO)6] (3), and [2-(Me2NCH2)C6H4SbFe2(CO)8] (4) by reactions of distibanes with Fe2(CO)9, crystal structures of 1–4 and DFT calculations of 1 are reported.

Mots clés: Physical Sciences

Hans Joachim Breunig, Enno Lork, Ovidiu Moldovan, Ciprian Ionut Rat. Reactions of Distibanes with [Fe2(CO)9]: Synthesis, Structure and DFT calculations of [(Et2Sb)4Fe4(CO)14], [(n-Pr2Sb)4Fe3(CO)10], [{(Me3SiCH2)2Sb}4Fe2(CO)6], and [2-(Me2NCH2)C6H4SbFe2(CO)8]. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2010, ⟨10.1002/zaac.200900547⟩. ⟨hal-00552436⟩