%0 Journal Article %T Structural and photoluminescence properties of ZnO thin films prepared by sol-gel process %+ Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS) %+ Laboratoire de technologies industrielles (LTI) %+ Institut d'Electronique du Solide et des Systèmes (InESS) %A Petersen, J. %A Brimont, Christelle %A Gallart, M. %A Cregut, O. %A Schmerber, G. %A Gilliot, P. %A Honerlage, B. %A Ulhaq-Bouillet, C. %A Rehspringer, J. L. %A Leuvrey, C. %A Colis, S. %A Aubriet, H. %A Becker, C. %A Ruch, D. %A Slaoui, A. %A Dinia, A. %< avec comité de lecture %Z GES:08-111 %@ 0021-8979 %J Journal of Applied Physics %I American Institute of Physics %V 104 %P 113539 %8 2008 %D 2008 %R 10.1063/1.3021358 %K ZINC-OXIDE FILMS %K MAGNETIC SEMICONDUCTORS %K OPTICAL-PROPERTIES %K EXCITON %K FERROMAGNETISM %K EPILAYERS %K GROWTH %Z Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Journal articles %X The present study focuses on the structural and optical properties of ZnO thin films fabricated by sol-gel process and spin coated onto Si (100) and quartz substrates. The ZnO films have a hexagonal wurtzite structure with a grain size of about 50 nm. The x-ray photoelectron spectroscopy measurements reveal the presence of Zn2+ and of zinc hydroxyl groups at the film. Optical properties were studied by photoluminescence (PL) and absorption spectroscopy at low and room temperatures. The absorption spectrum is dominated by a sharp excitonic peak at room and low temperatures. At room temperature, PL observations show two transitions: one near the absorption edge in the ultraviolet (UV) region and the second centered at 640 nm, characteristic of the deep electronic levels in the bandgap. The spectrum at 6 K is dominated by donor bound exciton lines and donor-acceptor pair transitions. LO-phonon replica and two-electron satellite transitions are also observed. These optical characteristics are a signature of good structural quality of the films. c 2008 American Institute of Physics. [DOI: 10.1063/1.3021358] %G English %L hal-00545174 %U https://hal.science/hal-00545174 %~ CNRS %~ UNIV-STRASBG %~ SITE-ALSACE