THEORETICAL STUDY OF COUPLING MECHANISMS BETWEEN OXYGEN DIFFUSION, CHEMICAL REACTION, MECHANICAL STRESSES IN A SOLID-GAS REACTIVE SYSTEM

Nicolas Creton (1) , Virgil Optasanu (1) , Tony Montesin (1) , Sébastien Garruchet (1)

1 ICB - Laboratoire Interdisciplinaire Carnot de Bourgogne

This paper offers a study of oxygen dissolution into a solid, and its consequences on the mechanical behaviour of the material. In fact, mechanical strains strongly influence the oxidation processes and may be, in some materials, responsible for cracking. To realize this study, mechanical considerations are introduced into the classical diffusion laws. Simulations were made for the particular case of uranium dioxide, which undergoes the chemical fragmentation. According to our simulations, the hypothesis of a compression stress field into the oxidised UO2 compound near the internal interface is consistent with some oxidation mechanisms of oxidation experimentally observed. More generally, this work will be extended to the simulation to an oxide layer growth on a metallic substrate.

Domaines: Mécanique des matériaux [physics.class-ph]; Mécanique des matériaux [physics.class-ph]; Chimie-Physique [physics.chem-ph]

Nicolas Creton, Virgil Optasanu, Tony Montesin, Sébastien Garruchet. THEORETICAL STUDY OF COUPLING MECHANISMS BETWEEN OXYGEN DIFFUSION, CHEMICAL REACTION, MECHANICAL STRESSES IN A SOLID-GAS REACTIVE SYSTEM. Annales de Chimie - Science des Matériaux, 2008, 33/Suppl.1, pp.165-172. ⟨10.3166/acsm.33.supp1.165-172⟩. ⟨hal-00416586⟩