 |
|
|
|
| HAL: hal-00366191, version 1 |
| Detailed view |  Export this paper |
|
|
| Journal of Molecular Catalysis B: Enzymatic 57 (2009) 6-9 |
|
|
|
|
| Preparative scale enzymatic synthesis of D-sedoheptulose-7-phosphate from β-hydroxypyruvate and D-ribose-5-phosphate |
|
|
| Franck Charmantray 1Virgil Hélaine 1 |
|
|
| (2009) |
|
|
|
| An enzymatic method for ready access to D-sedoheptulose-7-phosphate on a preparative scale was developed, based on the irreversible transketolase-catalyzed reaction: β-hydroxypyruvate + D-ribose-5- phosphate → D-sedoheptulose-7-phosphate. D-Sedoheptulose-7-phosphate disodium salt was obtained in 81% overall yield determined using a standard curve obtained by LC/MS/MS. |
|
|
|
|
|
|
|
|
|
|
|
| 1: | Synthèse et étude de systèmes à intêret biologique (SEESIB) |
|
|
|
CNRS : UMR6504 – Université Blaise Pascal - Clermont-Ferrand II |
|
|
|
|
|
|
|
|
|
| Subject | : | Chemical Sciences/Catalysis |
|
|
| D-Sedoheptulose-7-phosphate – Biocatalysis – Transketolase |
|
|
|
| Attached file list to this document: | |||||
|
|||||
|
|
|
| hal-00366191, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00366191 | |
| oai:hal.archives-ouvertes.fr:hal-00366191 | |
| From: Stéphanie Bonnefoy | |
| Submitted on: Friday, 6 March 2009 10:17:10 | |
| Updated on: Friday, 6 March 2009 10:28:07 | |
