Odin stratospheric proxy NO_y measurements and climatology

S. Brohede (1) , C. A. Mclinden (2) , Jakub Urban (1) , C. S. Haley (3) , A. I. Jonsson (4) , D. Murtagh (1)

1 Department of Radio and Space Science [Göteborg]
2 ECCC - Environment and Climate Change Canada
3 CRESS - Centre for Research in Earth and Space Science [Toronto]
4 Department of Physics [Toronto]

Five years of OSIRIS (Optical Spectrograph and InfraRed Imager System) NO₂ and SMR (Sub-Millimetre Radiometer) HNO₃ observations from the Odin satellite, combined with data from a photochemical box model, have been used to construct a stratospheric proxy NO_y data set including the gases: NO, NO₂, HNO₃, 2×N₂O₅ and CIONO₂. This Odin NO_y climatology is based on all daytime measurements and contains monthly mean and standard deviation, expressed as mixing ratio or number density, as function of latitude or equivalent latitude (5° bins) on 17 vertical layers (altitude, pressure or potential temperature) between 14 and 46 km. Comparisons with coincident NO_y profiles from the Atmospheric Chemistry Experiment?Fourier Transform Spectrometer (ACE-FTS) instrument were used to evaluate several methods to combine Odin observations with model data. This comparison indicates that the most appropriate merging technique uses OSIRIS measurements of NO₂, scaled with model NO/NO₂ ratios, to estimate NO. The sum of 2×N₂O₅ and CIONO₂ is estimated from uncertainty-based weighted averages of scaled observations of SMR HNO₃ and OSIRIS NO₂. Comparisons with ACE-FTS suggest the precision (random error) and accuracy (systematic error) of Odin NO_y profiles are about 15% and 20%, respectively. Further comparisons between Odin and the Canadian Middle Atmosphere Model (CMAM) show agreement to within 20% and 2 ppb throughout most of the stratosphere except in the polar vortices. A particularly large disagreement within the Antarctic vortex in the upper stratosphere during spring indicates too strong descent of air in CMAM. The combination of good temporal and spatial coverage, a relatively long data record, and good accuracy and precision make this a valuable NO_y product for various atmospheric studies and model assessments.

Domaines: Océan, Atmosphère

S. Brohede, C. A. Mclinden, Jakub Urban, C. S. Haley, A. I. Jonsson, et al.. Odin stratospheric proxy NO_y measurements and climatology. Atmospheric Chemistry and Physics Discussions, 2008, 8 (2), pp.5847-5899. ⟨hal-00304048⟩