Applicability of condensation particle counters to measure atmospheric clusters

M. Sipilä (1, 2) , K. Lehtipalo (1) , M. Kulmala (1) , T. Petäjä (1) , H. Junninen (1) , P. P. Aalto (1) , H. E. Manninen (1) , E. Vartiainen (1) , I. Riipinen (1) , E.-M. Kyrö (1) , J. Curtius (3) , A. Kürten (4) , S. Borrmann (3, 4) , C. D. O'Dowd (5)

1 Department of Physical Sciences [Helsinki]
2 HIP - Helsinki Institute of Physics
3 IPA - Institute for Atmospheric Physics [Mainz]
4 MPIC - Max Planck Institute for Chemistry
5 School of Physics & Centre for Climate and Air Pollution Studies

The ambient and laboratory molecular and ion clusters were investigated. Here we present data on the ambient concentrations of both charged and uncharged molecular clusters as well as the performance of a pulse height condensation particle counter (PH-CPC) and an expansion condensation particle counter (E-CPC). The ambient molecular cluster concentrations were measured using both instruments, and they were deployed in conjunction with ion spectrometers and other aerosol instruments in Hyytiälä, Finland at the SMEAR II station during 1 March to 30 June 2007. The observed cluster concentrations varied and were from ca. 1000 to 100 000 cm^?3. Both instruments showed similar concentrations. The average size of detected clusters was approximately 1.8 nm. As the atmospheric measurements at sub 2-nm particles and molecular clusters are a challenging task, and we were most likely unable to detect the smallest clusters, the reported concentrations are our best estimates for minimum cluster concentrations in boreal forest environment.

Domaines: Océan, Atmosphère

M. Sipilä, K. Lehtipalo, M. Kulmala, T. Petäjä, H. Junninen, et al.. Applicability of condensation particle counters to measure atmospheric clusters. Atmospheric Chemistry and Physics Discussions, 2008, 8 (2), pp.4373-4405. ⟨hal-00303378⟩