Temperature dependence of secondary organic aerosol yield from the ozonolysis of ?-pinene

C. Stenby (1, 2) , U. Pöschl (3) , P. von Hessberg (1, 2) , M. Bilde (2) , O. J. Nielsen (2) , G. K. Moortgat (1)

1 Atmospheric Chemistry Department [MPIC]
2 CCAR - Copenhagen Chemistry Atmospheric Research
3 Biogeochemistry Department [Mainz]

The temperature dependence of secondary organic aerosol (SOA) formation from ozonolysis of ?-pinene was studied in a flow reactor at 263?303 K and 1007 hPa. The observed SOA yields were of similar magnitude as predicted by a two-product model based on detailed gas phase chemistry (Jenkin, 2004), reaching maximum values of 0.22?0.39 at high particle mass concentrations. However, the measurement data exhibited significant deviations (up to 50%) from the predicted linear dependence on inverse temperature. When fitting the measurement data with a two-product model, we found that both the partitioning coefficients (K_om,i) and the stoichiometric yields (?_i) of the low-volatile and semi-volatile species vary with temperature. The results indicate that not only the reaction product vapour pressures but also the relative contributions of different gas-phase or multiphase reaction channels are dependent on temperature. We suggest that the modelling of secondary organic aerosol formation in the atmosphere needs to take into account the effects of temperature on the pathways and kinetics of the involved chemical reactions as well as on the gas-particle partitioning of the reaction products.

Domaines: Océan, Atmosphère

C. Stenby, U. Pöschl, P. von Hessberg, M. Bilde, O. J. Nielsen, et al.. Temperature dependence of secondary organic aerosol yield from the ozonolysis of ?-pinene. Atmospheric Chemistry and Physics Discussions, 2006, 6 (5), pp.10275-10297. ⟨hal-00302200⟩