On the growth of nucleation mode particles: source rates of condensable vapor in polluted and clean environments

M. Kulmala (1) , T. Petäjä (1) , P. Mönkkönen (1) , I. K. Koponen (1) , M. Dal Maso (1) , P. P. Aalto (1) , K. E. J. Lehtinen (2) , V.-M. Kerminen (2)

1 Department of Physics [Helsinki]
2 FMI - Finnish Meteorological Institute

The growth properties of nucleation mode particles were investigated. The variation of source rates of condensable vapors in different locations and environmental conditions was analyzed. The measurements were performed in background stations in Antarctica and in Finnish Lapland and Boreal Forest stations (SMEAR I and SMEAR II) as well as in polluted urban sites in Athens, Marseille and New Delhi. Taking advantage of only the measured aerosol particles spectral evolution as a function of time the formation and growth properties of nucleation mode aerosols have been evaluated. The diameter growth-rate and condensation sink have been obtained from the measured size distribution dynamics. Using this growth rate and condensation sink, the concentration of condensable vapours and their source rate have been estimated. The growth rates and condensation sinks were between 0.3?20 nm h^?1 and 10^?4?0.07 s^?1, respectively. The corresponding source rate of condensable vapors varied more than 4 orders of magnitude from 10³ to over 10⁷ cm^?1 s^?1. The highest condensation sink and source rate values were observed in New Delhi and the smallest values in Antarctica.

Domaines: Océan, Atmosphère

M. Kulmala, T. Petäjä, P. Mönkkönen, I. K. Koponen, M. Dal Maso, et al.. On the growth of nucleation mode particles: source rates of condensable vapor in polluted and clean environments. Atmospheric Chemistry and Physics Discussions, 2004, 4 (5), pp.6943-6966. ⟨hal-00301483⟩