Ultra-violet absorption cross sections of isotopically substituted nitrous oxide species: ¹⁴N¹⁴NO, ¹⁵N¹⁴NO, ¹⁴N¹⁵NO and ¹⁵N¹⁵NO

P. von Hessberg (1) , J. Kaiser (2) , M. B. Enghoff (1) , C. A. Mclinden (3) , S. L. Sorensen (4) , T. Röckmann (2) , M. S. Johnson (1)

1 Department of Chemistry
2 MPIK - Max Planck Institute for Nuclear Physics
3 Air Quality Research Branch
4 Synchrotron Radiation Research

The isotopically substituted nitrous oxide species ¹⁴N¹⁴NO, ¹⁵N¹⁴NO, ¹⁴N¹⁵NO and ¹⁵N¹⁵NO were investigated by ultra-violet (UV) absorption spectroscopy. High precision cross sections were obtained for the wavelength range 181 to 218 nm at temperatures of 233 and 283 K. These data are used to calculate photolytic isotopic fractionation constants as a function of wavelength. The fractionation constants were used in a three-dimensional chemical transport model in order to simulate the actual fractionation of N₂O in the stratosphere, and the results were found to be in good agreement with field studies.

Domaines: Océan, Atmosphère

P. von Hessberg, J. Kaiser, M. B. Enghoff, C. A. Mclinden, S. L. Sorensen, et al.. Ultra-violet absorption cross sections of isotopically substituted nitrous oxide species: ¹⁴N¹⁴NO, ¹⁵N¹⁴NO, ¹⁴N¹⁵NO and ¹⁵N¹⁵NO. Atmospheric Chemistry and Physics Discussions, 2004, 4 (3), pp.2333-2378. ⟨hal-00301187⟩