Phosphaalkenes, phospholyls and phosphinines : New tools in coordination chemistry and catalysis

Pascal Le Floch (1)

1 DCPH - Laboratoire Hétéroéléments et Coordination

This review covers recent achievements in the area of low coordinate phosphorus ligands featuring P=C double bonds such as phosphaalkenes, phospholide-based complexes and phosphinines. The most significant developments are presented and discussed for each class of ligands. Particular attention has been paid to the use of these new systems as ligands in homogeneous catalysis.

Mots clés: Phosphaalkene; phosphorus derivatives; phospholide-based complexes

Domaines: Chimie de coordination

Pascal Le Floch. Phosphaalkenes, phospholyls and phosphinines : New tools in coordination chemistry and catalysis. Coordination Chemistry Reviews, 2006, 250, pp.267. ⟨10.1016/j.ccr.2005.04.032⟩. ⟨hal-00086182⟩