Rheological study of an hydrate slurry for air conditionning application

Myriam Darbouret (1) , Michel Cournil (2, 3, 4) , Jean-Michel Herri (2, 3, 4)

1 IFPEN - IFP Energies nouvelles
2 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
3 GENERIC-ENSMSE - Département Géochimie, environnement, écoulement, réacteurs industriels et cristallisation
4 LPMG-EMSE - Laboratoire des Procédés en Milieux Granulaires

Under atmospheric pressure condition and tempertures between 0°C and +12°C, Tetra-n-ButylAmmonium bromide (TBAB) aqueous solutions crystallise into hydrate slurries. These slurries seem to be well appropriate for cold storage and transportation in the case of air-conditionning applications. We focus here on the crystallisation and the rheological properties of TBAB hydrates slurries. Once the crystallisation conditions described, we propose an experimental analysis of their flow behaviour. The experimental device is made up of a brushed surface heat exchanger in which the hydrates slurry is generated, and of a mesasurement loop. The flow behaviour of the slurry is characterised through flow rates and pressure drops measurements. We obtain flow curves of hydrates slurries depending on the volume fraction of hydrate solid particles. In the range of shear rate investigated, hydrate slurries behave as Bingham fluids. We propose a method of determining their apparent viscosities and yield shear stress versus the volume fraction hydrates.

Keywords: rheology; two-phase flow; heat transportation; air-conditioning

Domains: Chemical and Process Engineering; Other

Myriam Darbouret, Michel Cournil, Jean-Michel Herri. Rheological study of an hydrate slurry for air conditionning application. Fifth International Conference on Gas Hydrates (ICGH 5), Tromdheim, Norvège, 13 au 16 juin 2005, Jun 2005, Tromdheim, Norway. Volume 1 pp. 294-299. ⟨hal-00008245⟩