Surfactant-free single-layer graphene in water
Résumé
Dispersing graphite in water to obtain true (single-layer) graphene in bulk quantity in a liquid has been an unreachable
goal for materials scientists in the past decade. Similarly, a diagnostic tool to identify solubilized graphene in situ has been
long awaited. Here we show that homogeneous stable dispersions of single-layer graphene (SLG) in water can be obtained
by mixing graphenide (negatively charged graphene) solutions in tetrahydrofuran with degassed water and evaporating
the organic solvent. In situ Raman spectroscopy of these aqueous dispersions shows all the expected characteristics of
SLG. Transmission electron and atomic force microscopies on deposits confirm the single-layer character. The resulting
additive-free stable water dispersions contain 400 m2 l–1 of developed graphene surface. Films prepared from these
dispersions exhibit a conductivity of up to 32 kS m–1.