Relaxor Ferroelectrics: Back to the Single-Soft-Mode Picture.

Bernard Hehlen (1) , Maryam Al Majzoub Al Sabbagh (1) , Ali Al-Zein , J Hlinka

1 L2C - Laboratoire Charles Coulomb

The fluctuations of electric polarization in a disordered ferroelectric substance, relaxor crystal PbMg_{1/3}Nb_{2/3}O_{3} (PMN), were studied using a nonlinear inelastic light-scattering technique, hyper-Raman scattering, within a 5-100  cm^{-1} spectral interval and in a broad temperature range from 20 to 900 K. The split ferroelectric mode reveals a local anisotropy of up to about 400 K. Spectral anomalies observed at higher temperatures are explained as due to avoided crossing of the single primary polar soft mode with a temperature-independent, nonpolar spectral feature near 45  cm^{-1}, known from Raman scattering. The temperature changes of the vibrational modes involved in the measured fluctuation spectra of PMN were captured in a simple model that accounts for the temperature dependence of the dielectric permittivity as well. The observed slowing down of the relaxational dynamics directly correlates with the huge increase of the dielectric permittivity.

Mots clés: soft mode; hyper-Raman; ferroelectric relaxors; vibrations

Domaines: Systèmes désordonnés et réseaux de neurones [cond-mat.dis-nn]

Bernard Hehlen, Maryam Al Majzoub Al Sabbagh, Ali Al-Zein, J Hlinka. Relaxor Ferroelectrics: Back to the Single-Soft-Mode Picture.. Physical Review Letters, 2016, 117 (15), pp.155501. ⟨10.1103/PhysRevLett.117.155501⟩. ⟨hal-01388588⟩