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Article Dans Une Revue Macromolecules Année : 2014

Unwinding dynamics of a helically wrapped polymer

Marco Baiesi
  • Fonction : Auteur
Enrico Carlon
  • Fonction : Auteur
Helmut Schiessel
  • Fonction : Auteur

Résumé

We study the rotational dynamics of a flexible polymer initially wrapped around a rigid rod and unwinding from it. This dynamics is of interest in several problems in biology and constitutes a fundamental instance of polymer relaxation from a state of minimal entropy. We investigate the dynamics of several quantities such as the total and local winding angles and metric quantities. The results of simulations performed in two and three dimensions, with and without self-avoidance, are explained by a theory based on scaling arguments and on a balance between frictional and entropic forces. The early stage of the dynamics is particularly rich, being characterized by three coexisting phases.

Dates et versions

hal-01052685 , version 1 (28-07-2014)

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Jean-Charles Walter, Marco Baiesi, Enrico Carlon, Helmut Schiessel. Unwinding dynamics of a helically wrapped polymer. Macromolecules, 2014, 47, pp.4840-4846. ⟨10.1021/ma500635h⟩. ⟨hal-01052685⟩
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